Effect of Experimental Parameters on the Formation of Hydrogels by Polyelectrolyte Complexation of Carboxymethylcellulose, Carboxymethyl Starch, and Alginic Acid with Chitosan

Elizabeth Henao Mejía; Héctor Contreras; Ezequiel Delgado; Germán Quintana

doi:10.1155/2019/3085691

Effect of Experimental Parameters on the Formation of Hydrogels by Polyelectrolyte Complexation of Carboxymethylcellulose, Carboxymethyl Starch, and Alginic Acid with Chitosan

Elizabeth Henao Mejía, Héctor Contreras, Ezequiel Delgado, Germán Quintana

Research output: Contribution to journal › Article › Research › peer-review

7 Scopus citations

Abstract

Differences in morphology, pH, and electric charge of chitosan (CS) based hydrogels prepared by complexation with carboxymethylcellulose (CMC), carboxymethylated starch (CMS), and alginic acid (AA) at different polymers ratios and changing the order of addition were studied. CMC/CS and AA/CS hydrogels were amorphous and porous three-dimensional networks, with smaller pores at higher anionic polymer/CS ratios. Gelation time increased the agglomeration in the case of CMC/CS and CMS/CS gels. CMC/CS gels showed negative zeta potential values around -372 mV to -51 mV and CMS/CS gels in the range of -526 mV and -158 mV.

Original language	English
Article number	3085691
Journal	International Journal of Chemical Engineering
Volume	2019
DOIs	https://doi.org/10.1155/2019/3085691
State	Published - 2019

Bibliographical note

Funding Information:
2e authors are grateful to the Alianza del Pacifico México for the financial support of the research stay at the Departamento de Madera, Celulosa y Papel of the Uni-versidad de Guadalajara. 2e authors also acknowledge the support provided by Colciencias for financing the researcher and CIDI (UPB) for the financial support through internal project.

Publisher Copyright:
© 2019 Elizabeth Henao Mejía et al.

Access to Document

10.1155/2019/3085691

Cite this

@article{3c62995001a04dd0a16e17b14b80e9df,

title = "Effect of Experimental Parameters on the Formation of Hydrogels by Polyelectrolyte Complexation of Carboxymethylcellulose, Carboxymethyl Starch, and Alginic Acid with Chitosan",

abstract = "Differences in morphology, pH, and electric charge of chitosan (CS) based hydrogels prepared by complexation with carboxymethylcellulose (CMC), carboxymethylated starch (CMS), and alginic acid (AA) at different polymers ratios and changing the order of addition were studied. CMC/CS and AA/CS hydrogels were amorphous and porous three-dimensional networks, with smaller pores at higher anionic polymer/CS ratios. Gelation time increased the agglomeration in the case of CMC/CS and CMS/CS gels. CMC/CS gels showed negative zeta potential values around -372 mV to -51 mV and CMS/CS gels in the range of -526 mV and -158 mV.",

author = "Mej{\'i}a, {Elizabeth Henao} and H{\'e}ctor Contreras and Ezequiel Delgado and Germ{\'a}n Quintana",

note = "Publisher Copyright: {\textcopyright} 2019 Elizabeth Henao Mej{\'i}a et al.",

year = "2019",

doi = "10.1155/2019/3085691",

language = "Ingl{\'e}s",

volume = "2019",

journal = "International Journal of Chemical Engineering",

issn = "1687-806X",

publisher = "Hindawi Publishing Corporation",

}

Effect of Experimental Parameters on the Formation of Hydrogels by Polyelectrolyte Complexation of Carboxymethylcellulose, Carboxymethyl Starch, and Alginic Acid with Chitosan. / Mejía, Elizabeth Henao; Contreras, Héctor; Delgado, Ezequiel et al.
In: International Journal of Chemical Engineering, Vol. 2019, 3085691, 2019.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Effect of Experimental Parameters on the Formation of Hydrogels by Polyelectrolyte Complexation of Carboxymethylcellulose, Carboxymethyl Starch, and Alginic Acid with Chitosan

AU - Mejía, Elizabeth Henao

AU - Contreras, Héctor

AU - Delgado, Ezequiel

AU - Quintana, Germán

PY - 2019

Y1 - 2019

N2 - Differences in morphology, pH, and electric charge of chitosan (CS) based hydrogels prepared by complexation with carboxymethylcellulose (CMC), carboxymethylated starch (CMS), and alginic acid (AA) at different polymers ratios and changing the order of addition were studied. CMC/CS and AA/CS hydrogels were amorphous and porous three-dimensional networks, with smaller pores at higher anionic polymer/CS ratios. Gelation time increased the agglomeration in the case of CMC/CS and CMS/CS gels. CMC/CS gels showed negative zeta potential values around -372 mV to -51 mV and CMS/CS gels in the range of -526 mV and -158 mV.

AB - Differences in morphology, pH, and electric charge of chitosan (CS) based hydrogels prepared by complexation with carboxymethylcellulose (CMC), carboxymethylated starch (CMS), and alginic acid (AA) at different polymers ratios and changing the order of addition were studied. CMC/CS and AA/CS hydrogels were amorphous and porous three-dimensional networks, with smaller pores at higher anionic polymer/CS ratios. Gelation time increased the agglomeration in the case of CMC/CS and CMS/CS gels. CMC/CS gels showed negative zeta potential values around -372 mV to -51 mV and CMS/CS gels in the range of -526 mV and -158 mV.

UR - http://www.scopus.com/inward/record.url?scp=85063132563&partnerID=8YFLogxK

U2 - 10.1155/2019/3085691

DO - 10.1155/2019/3085691

M3 - Artículo

AN - SCOPUS:85063132563

SN - 1687-806X

VL - 2019

JO - International Journal of Chemical Engineering

JF - International Journal of Chemical Engineering

M1 - 3085691

ER -

Effect of Experimental Parameters on the Formation of Hydrogels by Polyelectrolyte Complexation of Carboxymethylcellulose, Carboxymethyl Starch, and Alginic Acid with Chitosan

Abstract

Bibliographical note

Access to Document

Fingerprint

Cite this