Pyrazolone-based nitrido complexes: Synthesis and nitrogen transfer to alkenes

Fredy R. Pérez; Julio Belmar; Yanko Moreno; Ricardo Baggio; Octavio Peña

doi:10.1039/b415101a

Pyrazolone-based nitrido complexes: Synthesis and nitrogen transfer to alkenes

Fredy R. Pérez, Julio Belmar, Yanko Moreno, Ricardo Baggio, Octavio Peña

Research output: Contribution to journal › Article in an indexed scientific journal › peer-review

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Abstract

The first examples of alkylpyrazolone based nitridomanganese(v) complexes are here reported. Styrene was used as a test substrate to study the complex's ability to transfer nitrogen in stoichiometric reactions. Preliminary trials yielded 75 to 91% of N-(2-hydroxy-1-phenylethyl)-2,2,2-trifluoroacetamide. An X-ray crystal structure for one of the nitrido complexes is also provided.

Original language	English
Pages (from-to)	283-287
Number of pages	5
Journal	New Journal of Chemistry
Volume	29
Issue number	2
DOIs	https://doi.org/10.1039/b415101a
State	Published - Feb 2005
Externally published	Yes

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abstract = "The first examples of alkylpyrazolone based nitridomanganese(v) complexes are here reported. Styrene was used as a test substrate to study the complex's ability to transfer nitrogen in stoichiometric reactions. Preliminary trials yielded 75 to 91% of N-(2-hydroxy-1-phenylethyl)-2,2,2-trifluoroacetamide. An X-ray crystal structure for one of the nitrido complexes is also provided.",

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AU - Pérez, Fredy R.

AU - Belmar, Julio

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AU - Baggio, Ricardo

AU - Peña, Octavio

PY - 2005/2

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AB - The first examples of alkylpyrazolone based nitridomanganese(v) complexes are here reported. Styrene was used as a test substrate to study the complex's ability to transfer nitrogen in stoichiometric reactions. Preliminary trials yielded 75 to 91% of N-(2-hydroxy-1-phenylethyl)-2,2,2-trifluoroacetamide. An X-ray crystal structure for one of the nitrido complexes is also provided.

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M3 - Artículo en revista científica indexada

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JO - New Journal of Chemistry

JF - New Journal of Chemistry

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Pyrazolone-based nitrido complexes: Synthesis and nitrogen transfer to alkenes

Abstract

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