Carbon xerogel microspheres and monoliths from resorcinol-formaldehyde mixtures with varying dilution ratios: Preparation, surface characteristics, and electrochemical double-layer capacitances

Zulamita Zapata-Benabithe, Francisco Carrasco-Marín, Juan De Vicente, Carlos Moreno-Castilla

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    44 Citas (Scopus)

    Resumen

    Carbon xerogels in the form of microspheres and monoliths were obtained from the sol-gel polymerization of resorcinol and formaldehyde in the presence of potassium carbonate as catalyst, using water as solvent and two different molar dilution ratios. The objectives of this study were as follows: to investigate the effect of the dilution ratio, polymerization reaction time, and temperature on the rheological properties of the sols used to prepare the carbon xerogel microspheres and monoliths; and to determine the influence of their preparation methods and shapes on their surface characteristics and electrochemical double-layer (EDL) capacitance. An increase in the molar dilution ratio produced a decrease in the apparent activation energy of the sol-gel transition. Carbon xerogel microspheres were steam-activated at different burnoff percentages. The morphology, surface area, porosity, and surface chemistry of samples were determined. The main difference between the carbon xerogel microspheres and monoliths was that the latter are largely mesoporous. Better electrochemical behavior was shown by carbon xerogels in monolith than in microsphere form, but higher gravimetric and volumetric capacitances were found in activated carbon xerogel microspheres than in carbon xerogel monoliths.

    Idioma originalInglés
    Páginas (desde-hasta)6166-6173
    Número de páginas8
    PublicaciónLangmuir
    Volumen29
    N.º20
    DOI
    EstadoPublicada - 21 may. 2013

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