TY - JOUR
T1 - Experimental-modeling study of phase equilibria, densities, and viscosities for the propanenitrile-decane mixture at low pressure
AU - Velásquez, Jorge A.
AU - Correa, María L.
AU - Cardona, Luis F.
AU - Forero, Luis A.
N1 - Publisher Copyright:
© 2021 American Chemical Society.
PY - 2021/2/11
Y1 - 2021/2/11
N2 - In this work, experimental data for vapor-liquid equilibria at 84.49 kPa, densities, and viscosities at 318.15 K are reported for the propanenitrile-decane mixture. To validate the methodology and the equipment selected to perform, the experimental study data for the ethanol-water mixture were measured and it was found that values are consistent with other data reported in the literature. After validation, experimental data for the propanenitrile + decane mixture were measured including liquid-liquid and vapor-liquid equilibria, densities, and viscosities. Finally, phase equilibria and densities were modeled using a modified Peng-Robinson equation of state. Also, the viscosity model proposed by Derevich was used to describe viscosities of pure substances and the Eyring-Wilson-Porter mixing rule was used to predict the viscosity of liquid mixtures. According to the obtained results, the models selected describe the measured thermodynamic and transport properties with low deviations.
AB - In this work, experimental data for vapor-liquid equilibria at 84.49 kPa, densities, and viscosities at 318.15 K are reported for the propanenitrile-decane mixture. To validate the methodology and the equipment selected to perform, the experimental study data for the ethanol-water mixture were measured and it was found that values are consistent with other data reported in the literature. After validation, experimental data for the propanenitrile + decane mixture were measured including liquid-liquid and vapor-liquid equilibria, densities, and viscosities. Finally, phase equilibria and densities were modeled using a modified Peng-Robinson equation of state. Also, the viscosity model proposed by Derevich was used to describe viscosities of pure substances and the Eyring-Wilson-Porter mixing rule was used to predict the viscosity of liquid mixtures. According to the obtained results, the models selected describe the measured thermodynamic and transport properties with low deviations.
UR - http://www.scopus.com/inward/record.url?scp=85100109321&partnerID=8YFLogxK
U2 - 10.1021/acs.jced.0c00884
DO - 10.1021/acs.jced.0c00884
M3 - Artículo
AN - SCOPUS:85100109321
SN - 0021-9568
VL - 66
SP - 1089
EP - 1100
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 2
ER -