Pyrazolone-based nitrido complexes: Synthesis and nitrogen transfer to alkenes

Fredy R. Pérez; Julio Belmar; Yanko Moreno; Ricardo Baggio; Octavio Peña

doi:10.1039/b415101a

Pyrazolone-based nitrido complexes: Synthesis and nitrogen transfer to alkenes

Fredy R. Pérez, Julio Belmar, Yanko Moreno, Ricardo Baggio, Octavio Peña

Producción científica: Contribución a una revista › Artículo en revista científica indexada › revisión exhaustiva

13 Citas (Scopus)

Resumen

The first examples of alkylpyrazolone based nitridomanganese(v) complexes are here reported. Styrene was used as a test substrate to study the complex's ability to transfer nitrogen in stoichiometric reactions. Preliminary trials yielded 75 to 91% of N-(2-hydroxy-1-phenylethyl)-2,2,2-trifluoroacetamide. An X-ray crystal structure for one of the nitrido complexes is also provided.

Idioma original	Inglés
Páginas (desde-hasta)	283-287
Número de páginas	5
Publicación	New Journal of Chemistry
Volumen	29
N.º	2
DOI	https://doi.org/10.1039/b415101a
Estado	Publicada - feb. 2005
Publicado de forma externa	Sí

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abstract = "The first examples of alkylpyrazolone based nitridomanganese(v) complexes are here reported. Styrene was used as a test substrate to study the complex's ability to transfer nitrogen in stoichiometric reactions. Preliminary trials yielded 75 to 91% of N-(2-hydroxy-1-phenylethyl)-2,2,2-trifluoroacetamide. An X-ray crystal structure for one of the nitrido complexes is also provided.",

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T2 - Synthesis and nitrogen transfer to alkenes

AU - Pérez, Fredy R.

AU - Belmar, Julio

AU - Moreno, Yanko

AU - Baggio, Ricardo

AU - Peña, Octavio

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AB - The first examples of alkylpyrazolone based nitridomanganese(v) complexes are here reported. Styrene was used as a test substrate to study the complex's ability to transfer nitrogen in stoichiometric reactions. Preliminary trials yielded 75 to 91% of N-(2-hydroxy-1-phenylethyl)-2,2,2-trifluoroacetamide. An X-ray crystal structure for one of the nitrido complexes is also provided.

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M3 - Artículo en revista científica indexada

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Pyrazolone-based nitrido complexes: Synthesis and nitrogen transfer to alkenes

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